Control volume surrounding an steady evaporation wave. Reactor pressure atmospheres Vapor- liquid ratio Observed aimljmis mole % Equilibrium Liquid Vapor mole % mole %. Four major steps are discerned during the transition from adsorption to capillary-dominated imbibition (Fig. The modified unitary approach of Philip (1977a), supplemented by adsorption terms presented by Iwamatsu and Horii (1996), provides a means of calculating equilibrium liquid-vapor interfaces for various chemical potentials during drainage and imbibition. As conditions are changed, the system adjusts itself until the system reaches equilibrium again either the liquid which is present evaporates, or the vapor condenses. The vapor pressure of a liquid in equilibrium with its vapor cannot be treated like an ideal gas that obeys the gas laws the equilibrium ( liquid vapor) controls the vapor pressure.
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